I feel like that's more of Damon's bullshit. He's experimenting with being ethical and having friends, so he has tender new friend feelings that get hurt when one of his friends gets hurt. So he tries to be like Stefan or Elena, i.e. he tries to reprimand the bad person for being bad, and he can try it on Caroline because it's only Caroline, after all. And now he's disappointed when she doesn't take him seriously.
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