HG Wells, Cara (LOTS), Lana (Archer), Harley Quinn, Santanna (Glee).
All canon!
ETA: And I forgot Sharon Tyler! Okay, I'd probably swap out Lana or Santanna for Sharon.
Also, your questions: characters who the WRITERS might say are straight but do not present that way at all. I'm thinking of characters like Jess or Kate Bishop who are shown to have relationships with the opposite sex but also have moments where you go, 'okay, character you are not straight or at least not 100% straight.'
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timeasmymeasure
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All canon!
ETA: And I forgot Sharon Tyler! Okay, I'd probably swap out Lana or Santanna for Sharon.
Also, your questions: characters who the WRITERS might say are straight but do not present that way at all. I'm thinking of characters like Jess or Kate Bishop who are shown to have relationships with the opposite sex but also have moments where you go, 'okay, character you are not straight or at least not 100% straight.'